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Comprehensive methodology for Staphylococcus aureus lipidomics by liquid chromatography and quadrupole time-of-flight mass spectrometry

  • W. Hewelt-Belka
  • J. Nakonieczna
  • M. Belka
  • T. Bączek
  • J. Namieśnik
  • A. Kot-Wasik

Staphylococcus aureus is a common pathogen known to cause relatively minor infections as well as severe disorders in humans. Although there is fair amount of published data concerning various aspects of its biology, epidemiology, genetics, etc., there is still a scarce amount of data presenting reliable and thorough investigations regarding high-throughput analysis of total S. aureus lipid content. Therefore, the aim of this study.

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Analysis of volatile fraction of hybrid fruit pulp using Proton Transfer Reaction – Time-Of-Flight Mass Spectrometry

Fruits and vegetables are important ingredients in human diet. Because of this, it is very important to know their exact composition and to control their quality. Based on the aroma of food products, it is possible to pre-evaluate their quality and freshness. The aim of this work was to characterize the volatile fraction of the hybrid fruit ‘sweetie’ using the modern analytical device PTR-TOFMS. Hybrid fruit samples are human-made.

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A new method for real-time monitoring of volatiles in frying fumes using proton transfer reaction mass spectrometry with time-of-flight analyse

To safeguard the consumers’ well-being, it is necessary to develop novel methods for determination of carcinogens in food, including volatiles generated during frying. The currently used procedures for analysis of volatile fraction of vegetable oils are not based on real-time measurements and thus do not enable the determination of carcinogenic compounds in frying fumes; instead, only the headspace or liquid fraction is sampled.

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Solid phase microextraction–comprehensive twodimensional gas chromatography–time-of-flight mass spectrometry: a new tool for determining PAHs in airport runoff water samples

fundamental aspect of airport operations is the pollution caused by airport runoff waters. Polycyclic aromatic hydrocarbons (PAHs) are one of the most important groups of xenobiotics which are commonly found in runoff water originating from airports. Only very limited data on the analysis of airport runoff water have been published until now. Therefore, a reliable and accurate analytical method based on headspace solid-phase microextraction.

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Determination of parent and methylated polycyclic aromatic hydrocarbons in water samples by dispersive liquid–liquid microextraction–two dimensional gas chromatography–time-of-flight mass spectrometry

Polycyclic aromatic hydrocarbons (PAHs) are contaminants frequently found in environmental waters. Owing to their toxic effects, it is important to develop analytical methodologies that allow their fast and reliable determination. Dispersive liquid–liquid microextraction (DLLME) allows a quick extraction of analytes with little organic solvent consumption. The best results regarding sample preparation are obtained when 40 mL of.

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Two-Dimensional Gas Chromatography Coupled With Mass Spectrometry in Food Analysis

The development of instrumental analytical techniques provided the opportunity for in-depth characterization of many food matrices. In particular, the use of gas chromatography coupled with mass spectrometry gives impressive results in terms of quality and authenticity testing, conducting food freshness evaluations and contamination assessments. A new variant of gas chromatography, namely two-dimensional gas chromatography (GC.

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Rapid Characterization of the Human Breast Milk Lipidome Using a Solid-Phase Microextraction and Liquid Chromatography-Mass Spectrometry-Based Approach.

Human breast milk (HBM) is a biofluid consisting of various biomolecules such as proteins, lipids, carbohydrates, minerals and bioactive substances. Due to its unique and complex composition, HBM provides not only nutritional components required for the growth of the infant, but also additional protection against infections. Global insight into the composition of HBM is crucial to understanding the health benefits infants receive.

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Direct Analysis of Samples of Various Origin and Composition Using Specific Types of Mass Spectrometry

One of the major sources of error that occur during chemical analysis utilizing the more conventional and established analytical techniques is the possibility of losing part of the analytes during the sample preparation stage. Unfortunately, this sample preparation stage is required to improve analytical sensitivity and precision. Direct techniques have helped to shorten or even bypass the sample preparation stage; and in this.

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Chromatographic and Spectroscopic Identification and Recognition of Natural Dyes, Uncommon Dyestuff Components, and Mordants: Case Study of a 16th Century Carpet with Chintamani Motifs

  • O. Otłowska
  • M. Ślebioda
  • A. Kot-Wasik
  • J. Karczewski
  • M. Śliwka-Kaszyńska

A multi-tool analytical practice was used for the characterisation of a 16th century carpet manufactured in Cairo. A mild extraction method with hydrofluoric acid has been evaluated in order to isolate intact flavonoids and their glycosides, anthraquinones, tannins, and indigoids from fibre samples. High-performance liquid chromatography coupled to spectroscopic and mass spectrometric detectors was used for the identification of.

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Rapid and Green Separation of Mono- and Diesters of Monochloropropanediols by Ultrahigh Performance Supercritical Fluid Chromatography–Mass Spectrometry Using Neat Carbon Dioxide as a Mobile Phase

  • F. Jumaah
  • R. Marcinkowska
  • J. Gromadzka
  • J. Namieśnik
  • S. Essén
  • C. Turner
  • M. Sandahl

This study demonstrates the effect of column selectivity and density of supercritical carbon dioxide (SC-CO2) on the separation of monochloropropanediol (MCPD) esters, known as food toxicants, using SC-CO2 without addition of cosolvent in ultrahigh performance supercritical fluid chromatography–mass spectrometry (UHPSFC-MS). This study shows that over 20 2-monochloropropanediol (2-MCPD) and 3-monochloropropanediol (3-MCPD) mono-.

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The dispersive micro-solid phase extraction method for MS-based lipidomics of human breast milk*

A simple and rapid microextraction method ensuring high lipidome coverage was developed for liquid chromatography mass spectrometry (LC-MS)-based lipidomics of human breast milk. The dispersive microsolid phase extraction (D-µ-SPE) technique, coupled with the design of experiment (DoE) method, enabled the study of the influence of several conditions (desorption solvent, stationary phase ratio, and sorption and desorption time).

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Determination of Biogenic Amines in Wine Using Micellar Electrokinetic Chromatography

  • J. Płotka-Wasylka
  • E. Kłodzińska
  • J. Namieśnik

Production on a large-scale of fermented alcoholic drinks made from different kinds of fruits is carried out in homes. Although wine laws regulating home production exist, they do not include upper concentration limits of biogenic amines. Therefore, a quick and inexpensive way to determine BAs in wine is crucial. A new analytical method based on micellar electrokinetic chromatography has been developed for the separation of the.

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Qualitative analysis of phospholipids and their oxidised derivatives – used techniques and examples of their applications related to lipidomic research and food analysis

  • K. Parchem
  • S. Sasson
  • C. Ferreri
  • A. Bartoszek-Pączkowska

Phospholipids (PLs) are important biomolecules that not only constitute structural building blocks and scaffolds of cell and organelle membranes, but also play a vital role in cell biochemistry and physiology. Moreover, dietary exogenous PLs are characterized by high nutritional value and other beneficial health effects, which are confirmed by numerous epidemiological studies. For this reason, PLs are of high interest in lipidomics.

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Direct measurements of odorous volatile organic compounds present in biosolids cakes by Proton Transfer Reaction – Mass Spectrometry Technique

This paper show the results of investigation of concentration of odorous chemical compounds emitted upon ageing of anaerobically stabilised biosolids that could contribute to the overall odour character of nuisance emissions. Biosolids samples from wastewater treatment plant were collected in spring time. Concentrations of volatile organic compounds using a US EPA flux hood and Proton Transfer Reaction-Time of Flight-Mass Spectrometry.

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Recent advances in assessing xenobiotics migrating from packaging material – A review

Migration of potentially toxic xenobiotics and their transformation products from packaging materials needs continuous monitoring efforts. This task requires utilizing both instrumental and biological methods as more and more novel materials reach market every year to serve consumers and reduce production costs. Unfortunately, these materials very often sneak past our legal regulations on their composition and emission of contaminants.

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Influence of chemical structure on physicochemical properties and thermal decomposition of the fully bio-based poly(propylene succinate-co-butylene succinate)s

In this work, two polyesters and four copolyesters were studied. All materials were synthesized to obtain the monomers dedicated for thermoplastic polyurethane elastomers. For this type of PUR, the monomers should characterize by appropriate selected physicochemical properties and macromolecular structure distribution, which depends on synthesis conditions. The study of chemical structure with extensive and knowledgeable analysis.

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Development of chromatographic and mass spectrometry conditions for untargeted lipidomic analysis of human breast milk

Human breast milk (HBM) is a complex biofluid containing components which are essential for the proper growth of the newborn (for example nutrients such as carbohydrates, proteins, lipids) and also bioactive substances. According to the literature, most of studies involving HBM nutrients investigations focused essentially on the determination of proteins. The molecular composition of lipids in HBM is not well known as the protein.

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The Current State-of-the-Art in the Determination of Pharmaceutical Residues in Environmental Matrices Using Hyphenated Techniques

Several thousand tons of pharmaceuticals and their transformation products (metabolites and degradation products) are introduced into the environment each year. They affect both human health and the environment, therefore, analytical procedures enabling the determination of a wide range of pharmaceuticals at trace levelswithminimal effort, time, and energy are required. Nowadays, hyphenated techniques are commonly applied in pharmaceutical.

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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples

Developed and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment.

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Application of gas chromatography–tandem mass spectrometry for the determination of amphetamine-type stimulants in blood and urine

  • M. Woźniak
  • M. Wiergowski
  • J. Aszyk
  • P. Kubica
  • J. Namieśnik
  • M. Biziuk

Amphetamine, methamphetamine, phentermine, 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxy-N-ethylamphetamine (MDEA) are the most popular amphetamine-type stimulants. The use of these substances is a serious societal problem worldwide. In this study, a method based on gas chromatography-tandem mass spectrometry (GC-MS/MS) with simple and rapid liquid-liquid extraction (LLE).

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Structure-rheology relationship of fully bio-based linear polyester polyols for polyurethanes – Synthesis and investigation

The synthesis of polyols from renewable substances as an alternative for petrochemical-based polyols play important matter in the polyurethane industry. In this work, the fully bio-based linear polyester polyols with different catalyst amounts were synthesized via two-step polycondensation method. The effect of various catalyst content on the structure and rheological behavior were established. Fourier Transform Infrared Spectroscopy.

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Ultimate biodegradability and ecotoxicity of orally administered antidiabetic drugs

  • M. Markiewicz
  • C. Jungnickel
  • S. Stolte
  • A. Białk-Bielińska
  • J. Kumirska
  • W. Mrozik

Hypoglycaemic pharmaceuticals are recently more and more frequently detected in the environment. In our previous study, we have shown that even though many of them undergo significant primary degradation some are transformed to stable products or undergo such transformation that a large part of the structure is still preserved. One of the main routes of elimination from wastewaters or surface waters is biodegradation and a lack.

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Environmental Fate of Two Psychiatric Drugs, Diazepam and Sertraline: Phototransformation and Investigation of their Photoproducts in Natural Waters

Experimental studies were conducted to investigate the photodegradation of diazepam and sertraline, two of the most frequently used psychiatric drugs, induced by xenon lamp irradiation, which overlap the sunlight spectra, and natural sunlight. Degradation kinetics was established indicating the occurrence of autocatalytic reactions. The application of liquid chromatography coupled to quadrupole time-of-flight mass spectrometry.

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The use of HPLC-Q-TOF-MS for comprehensive screening of drugs and psychoactive substances in hair samples and several “legal highs” products

Non-targeted screening of drugs present in herbal products, known as “legal high” drugs and in hair as a biological matrix commonly used in toxicological investigations was accomplished with the use of high pressure liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (HPLC-Q-TOF-MS). In total, 25 and 14 therapeutical drugs and psychoactive substances/metabolites were detected in investigated hair samples.

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Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry

Bisphenol A diglycidyl ether (BADGE), bisphenol F diglycydyl ether (BFDGE), and their related compounds are widely used as precursors in production of epoxy resins. The high reactivity of these compounds makes the development of analytical methodologies that ensure appropriate metrological accuracy crucial. Consequently, we aimed to determine whether and to what extent the composition of the solution and storage conditions affect.

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Complementary use of GCxGC–TOF–MS and statistics for differentiation of variety in biosolid samples

Formation of biosolid cakes, which are one of the main wastes generated in wastewater treatment plants, is connected with emission of many hazardous chemical compounds, including odoriferous ones. To optimize particular processes of biosolid cake processing, it is necessary to assess chemical composition of the gas mixtures containing the compounds released from the cakes. The paper proposes application of two-dimensional gas chromatography.

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Development of different methods for drugs and psychoactive substances extraction from hair samples and their identification based on HPLC-ESI-QTOF analysis

Over the past decade, the use of non-controlled designer drugs and drug of abuse has rapidly increased. Hair, as a human matrix, enables detection of drugs incorporated into its structure. Studies of presence and identification of drug metabolites in human hair samples has been performed using liquid chromatography electrospray ionization quadrupole time of flight mass spectrometry (HPLC-ESI-QTOF-MS) with steady alternation of.

Analysis of volatile fraction selected hybrid fruits using chromatographic techniques

At present, „healthy eating” is gaining in popularity. Many people associate this term with eating plenty of vegetables and fruits. The basic elements influencing the selection of fruit are their appearance and smell. Of course, their origin and impact on human health are also very important. In recent years, exotic fruits have become increasingly accessible, making them gaining popularity, even among Poles. You can also meet plants.

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Convenient identification of desulfoglucosinolates on the basis of mass spectra obtained during liquid chromatography-diode array-electrospray ionisation mass spectrometry analysis: Method verification for sprouts of different Brassicaceae species extracts

Over the past decade, glucosinolates (GLs) present in different tissues of Brassicaceae and their breakdown products, especially isothiocyanates formed after myrosinase catalyzed hydrolysis, have been regarded as not only environment friendly biopesticides for controlling soilborne pathogens, but most importantly as promising anticarcinogenic compounds. For these reasons, the identification and quantitative determination of the.

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Direct determination of cadaverine in the volatile fraction of aerobically stored chicken breast samples

To supplement the currently used methods for poultry meat shelf life assessment, it might be necessary to develop a technique for rapid headspace analysis of volatiles with no prior sample preparation step. Biogenic amines, in particular cadaverine, are considered meat spoilage indicators. Described in this article are the results of a preliminary investigation of the applicability of proton transfer reaction mass spectrometry.

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Comprehensive determination of flavouring additives and nicotine in e-cigarette refill solutions. Part I: Liquid chromatography-tandem mass spectrometry analysis

Liquid chromatography-tandem mass spectrometry with electrospray ionization (HPLC-ESI–MS/MS) methods were developed for the simultaneous determination of 42 flavouring compounds and nicotine in liquids for e-cigarettes. The chromatographic separation was performed using an Ace® Ultracore™ SuperC18™ (100 × 2.1 mm, 2.5 μm) column in both acidic and alkaline pH conditions to separate all the compounds. A simple “dilute & shoot” approach.

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Comprehensive determination of flavouring additives and nicotine in e-cigarette refill solutions. Part II: Gas-chromatography–mass spectrometry analysis

Flavouring compounds are an essential part of e-liquid products for cigarettes. In general, they are regarded as safe for ingestion, but they may have unrecognized risks when they are inhaled. In some cases, manufactures do not currently abide by the Tobacco Products Directive (2020/40/EU) and do not declare the detailed contents of e-liquids on their labels. To help evaluate the health impact of flavouring substances, there is.

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Determination of odour concentration by TD-GC×GC–TOF-MS and field olfactometry techniques

Field olfactometry is one of the sensory techniques used to determine odour concentration, in atmospheric air, directly in emission sources. A two-dimensional gas chromatography with time of flight mass spectrometer (GC×GC–TOF-MS) allows performing the chemical characterization of various groups of chemical compounds, even in complex mixtures. Application of these techniques enabled determination of odour concentration level in.

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Urine headspace analysis in medical diagnostics

The analysis of the volatile organic compounds in the bodily fluids such as urine may provide useful information on the patients’ general health. The potential application of urine headspace analysis could facilitate the diagnostics of various diseases such as metabolic disorders, urinary tract diseases and gastrointestinal conditions. Described in this paper are the currently available techniques of urine sample analysis as well.

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Lipidomics of Staphylococcus aureus – a new insight into the antibiotic resistant phenotype

  • W. Hewelt-Belka
  • J. Nakonieczna
  • M. Belka
  • T. Bączek
  • J. Namieśnik
  • A. Kot-Wasik

Staphylococcus aureus is an aggressive pathogen responsible for a variety of diseases, in cluding life-threatening sepsis. Many strains of these bacteria are resistant to multiple classes of antibiotics, which is a substantial clinical problem in the treatment of S. aureus infections. We developed a comprehensive untargeted lipidomic workflow, including sample preparation, liquid chromatography-quadrupole-time-of-flight mass spectrometry.

Fully bio-based poly(propylene succinate) synthesis and investigation of thermal degradation kinetics with released gases analysis

One of the most important information about polyesters is their thermal stability and phase transition tem- peratures. These characteristics give information about the promising behavior of the polyester during proces- sing. In this work, linear bio-based polyester polyols were prepared with the use of succinic acid and 1.3- propanediol (both with natural origin). As a polycondensation catalyst was used tetraisopropyl orthotitanate.

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Key-Marker Volatile Compounds in Aromatic Rice (Oryza sativa) Grains: An HS-SPME Extraction Method Combined with GC×GC-TOFMS

The aroma of rice essentially contributes to the quality of rice grains. For some varieties, their aroma properties really drive consumer preferences. In this paper, using a dynamic headspace solid-phase microextraction (HS-SPME) system coupled to a two-dimensional gas chromatography (GC×GC) using a time-of-flight mass spectrometric detector (TOFMS) and multivariate analysis, the volatile compounds of aromatic and non-aromatic.

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The Role of Electron Transfer in the Fragmentation of Phenyl and Cyclohexyl Boronic Acids

  • A. Lozano
  • B. Pamplona
  • T. Kilich
  • M. Łabuda
  • M. Mendes
  • J. Pereira-Da-Silva
  • G. García
  • P. Gois
  • F. Ferreira Da Silva
  • P. Limão-Vieira

In this study, novel measurements of negative ion formation in neutral potassium-neutral boronic acid collisions are reported in electron transfer experiments. The fragmentation pattern of phenylboronic acid is comprehensively investigated for a wide range of collision energies, i.e., from 10 to 1000 eV in the laboratory frame, allowing some of the most relevant dissociation channels to be probed. These studies were performed in.

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Synthesis and characterization of novel renewable polyesters based on 2,5-furandicarboxylic acid and 2,3-butanediol

  • E. Gubbels
  • L. Jasińska-Walc
  • C. Koning

Novel polyesters from 2,5-furandicarboxylic acid or 2,5-dimethyl-furandicarboxylate and 2,3-butanediol have been synthesized via bulk polycondensation catalyzed by titanium (IV) n-butoxide, tin (IV) ethylhexanoate, or zirconium (IV) butoxide. The polymers were analyzed by size exclusion chromatography, nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FTIR), matrix-assisted laser ionization-desorption.

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MRM–MS of marker peptides and their abundance as a tool for authentication of meat species and meat cuts in single-cut meat products

The abundance of protein markers in different types of meat cuts was explored in the context of authentication of raw meat (pork, beef and chicken) and processed meat products. Peptides originating from myoglobin (Mb) and myosin (My) were analyzed using multiple reaction monitoring mass spectrometry (MRM–MS). Analytical protocol was optimized for good repeatability (CV Full text available

Comprehensive two dimensional gas chromatography coupled with mass spectrometry as tool for characterization of the main pollutants present in atmospheric air in Gdansk

Nowadays, the technique that is commonly used to identify and quantify the chemical compounds in gas sample is gas chromatography. The separation resolution in gas chromatography can be improved by applying the modulation technique. In this paper present is the most important information regarding the pollutants present in atmospheric air. The areas in which the tests were carried out are one of the largest industrial zones in.

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Phototransformation of three selected pharmaceuticals, naproxen, 17α-Ethinylestradiol and tetracycline in water: Identification of photoproducts and transformation pathways

  • M. Śliwka-Kaszyńska
  • A. Jakimska-Nagórska
  • A. Wasik
  • A. Kot-Wasik

Transformation products (TPs) may be formed during various processes, however, it was proved that one of the main mechanisms responsible for degradation of pharmaceuticals in natural waters is photolysis. Three compounds were selected, tetracycline (TC), 17-α-ethinylestradiol (EE2) and naproxen (NAP), for degradation experiments which were performed using a xenon lamp emitting light with a spectrum closely approximating that of.

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Interaction of human serum albumin with volatiles and polyphenols from some berries

  • R. Beema
  • T. Dymerski
  • J. Namieśnik
  • Z. Jastrzębski
  • S. Vearasilp
  • S. Gorinstein

Headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (HS-SPME/GC GCeTOFMS) identified 19 and quantified 6 monoterpenes in gooseberries, blueberries and cranberries. As a protein model human serum albumin (HSA) was used in interaction with terpenes. Specific binding of terpenes to HSA under the physiological conditions was a result of the formation.

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Organic Acids and Polyphenols Determination in Polish Wines by Ultrasound-Assisted Solvent Extraction of Porous Membrane-Packed Liquid Samples

In the near future, Poland is going to have more and more favorable conditions for viticulture. Organic acids and polyphenols are among the most commonly analyzed compounds due to their beneficial properties for human health and their importance in the winemaking process. In this work, a new technique involving ultrasound-assisted solvent extraction of porous membrane-packed liquid samples (UASE-PMLS) was for the first time described.

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Analysis of volatile fraction of sweetie (Citrus maxima × Citrus paradisi) and its parent fruit using proton transfer reaction mass spectrometry

The quality of the fruit is affected by several main ingredients and the aroma plays a fundamental role during the selection of fruit by consumers. In the case where several fruit have similar aromas and only one of them has specific health properties, it is very important to find the differences in the volatile organic compounds (VOCs) composition to distinguish these samples. Such situations are often found for hybrid fruit.

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Blood concentrations of a new psychoactive substance 4-chloromethcathinone (4-CMC) determined in 15 forensic cases

  • E. Tomczak
  • M. Woźniak
  • M. Kata
  • M. Wiergowski
  • B. Szpiech
  • M. Biziuk

Purpose: The 4-chloromethcathinone (4-CMC) is a synthetic derivative of cathinone and belongs to new psychoactive substances. Neither data on the effects of 4-CMC on the human body, nor on nontoxic, toxic and lethal concentrations in biological materials have been published in the literature. This paper describes the results of an analysis of the blood concentrations of 4-CMC determined in 15 forensic cases related to nonfatal.

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Simultaneous determination of individual isothiocyanates in plant samples by HPLC-DAD-MS following SPE and derivatization with N-acetyl-l-cysteine

The procedure for the isothiocyanates (ITCs) determination that involves derivatization with N-acetyl-l-cysteine (NAC) and separation by HPLC was developed. Prior to derivatization, plant ITCs were isolated and purified using solid-phase extraction (SPE). The optimum conditions of derivatization are: 500 μL of isopropanolic eluate obtained by SPE combined with 500 μL of derivatizing reagent (0.2 M NAC and 0.2 M NaHCO3 in water).

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Funcionality assessment of Citrus Hysteria peel as a protective barrier using gas chromatography

The aim of this study was to analyse the volatile fractions of fruit peel and pulp using two-dimensional gas chromatography technique coupled with mass spectrometry. The isolation of the compounds was achieved by microextraction to the stationary phase from the headspace of the sample (HS-SPME). Mass spectrometry with time-of-flight analyser (TOF-MS) was used to identify the chemical compounds. There are no reports in the literature.

Determination of polycyclic aromatic hydrocarbons (PAHs) and other organic pollutants in freshwaters on the western shore of Admiralty Bay (King George Island, Maritime Antarctica).

  • M. Szopińska
  • D. Szumińska
  • R. Bialik
  • T. Dymerski
  • E. Rosenberg
  • Ż. Polkowska

Organic contamination in freshwater samples has never been investigated at the western shore of Admiralty Bay. Therefore, the presence of polycyclic aromatic hydrocarbons (PAHs) in five different sites distributed along a shore running from the Arctowski Station to the Baranowski Glacier was studied. Moreover, organic compounds such as n-alkanes, toluene and ethylbenzene were also noted. Increased ΣPAHs in late Austral summer 2020.

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Electron impact ionization and cationic fragmentation of the pyridazine molecules

Electron impact mass spectroscopy was used to investigate ionization and cationic fragmentation of the pyridazine (1,2 diazine), C4H4N2, molecules in the gas phase. The mass spectra were measured and the observed mass peaks assigned to the corresponding cations. The appearance energies of most of the cationic fragments were determined and the possible fragmentation processes are discussed. The total cross section for electron.

Natalia Anna Wójcik – Publikacje – MOST Wiedzy

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Synthesis, structural characterization, and thermal properties of Ca‐ and La‐doped soda‐lime glasses by laser melting
  • S. Ali
  • N. Wójcik
  • B. Jonson
  • E. Kamitsos
  • X. Li
  • J. Luo
  • D. Möncke

Laser melting techniques have been used in the preparation of unconventional glass compositions with high melting temperatures. Thus, we wanted to test the feasibility of using a CO2 laser in the preparation of nitrogen-rich oxynitride glasses and nitride silicate glasses. Melting from oxides and metallic raw materials, we wanted to study first glass formation and possible evaporation losses of the glass components. Two glass series.

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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
  • N. Wójcik
  • P. Kupracz
  • R. Barczyński
  • B. Jonson
  • S. Ali

Electrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap.

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The effect of nitrogen on the structure and thermal properties of beryllium-containing Na-(Li)-Si-O-N glasses
  • N. Wójcik
  • B. Jonson
  • D. Möncke
  • E. Kamitsos
  • H. Segawa
  • J. Karczewski
  • S. Ali

Two oxynitride glass series with the composition of 35Na2O-5BeO-(60-x)SiO2-xSi3N4 and 9Li2O- 27Na2O-5BeO-(59-x)SiO2-xSi3N4, were prepared. The glasses’ topography and structure were studied by Scanning Electron Microscopy and Raman spectroscopy. The composition was analyzed by Inductively Coupled Plasma Optical Emission Spectrometer, SEM-EDS and nitrogen and oxygen elemental analyzer. Na-(Li)-Be-silicate glasses were found to contain.

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The influence of Be addition on the structure and thermal properties of alkali-silicate glasses
  • N. Wójcik
  • S. Ali
  • D. Möncke
  • N. Tagiara
  • E. Kamitsos
  • H. Segawa
  • M. Eriksson
  • B. Jonson

Be-Na-(Li)-Si oxide glasses containing up to 15 mol% of BeO were prepared. Their structure was characterized by X-ray powder diffraction and Raman as well as infrared spectroscopic techniques, while their chemical compositions were examined by Inductively Coupled Plasma Optical Emission Spectrometry. All materials were found to be amorphous and contain Al contaminations from minor dissolution of the alumina crucibles. The results.

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Thermal, electrical, and magnetic properties of Fe2O3–PbO–SiO2 glass prepared by traditional melt-quenching and twin roller fast-cooling methods

In this study, Fe–Pb–Si oxide glasses containing between 12.5 and 17.5 mol% Fe2O3 were prepared using two different methods comprising traditional melt-quenching and twin roller fast-cooling techniques. The topography and structure of the materials obtained were characterized by X-ray powder diffraction and scanning electron microscopy. All of the materials were found to be amorphous. The topography of most of the glasses comprised.

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A method of determination of electrical conduction mechanisms in complex amorphous materials

A novel approach to determine conduction mechanisms in complex amorphous materials was presented and tested on a real system. In the first step of the presented method, total electrical admittance of the material is analyzed in order to separate a couple of processes, each of which can be described by Jonscher’s universal dielectric response. In the following step, a temperature dependence of dielectric response parameters of the.

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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
  • N. Wójcik
  • B. Jonson
  • R. Barczyński
  • P. Kupracz
  • D. Möncke
  • S. Ali

Sodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between.

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Influence of synthesis conditions on glass formation, structure and thermal properties in the Na 2 O-CaO-P 2 O 5 system doped with Si 3 N 4 and Mg
  • N. Wójcik
  • B. Jonson
  • D. Möncke
  • D. Palles
  • E. Kamitsos
  • E. Ghassemali
  • S. Seifeddine
  • M. Eriksson
  • S. Ali

Oxynitride phosphate glasses and glass-ceramics were prepared using new synthesis routes for phosphate glasses. Materials were melted from pre-prepared glass samples in the system Na-Ca-P-O with addition of Mg and/or Si3N4 powders under different preparation conditions. The melting process was conducted at 1000–1500 °C either under air or nitrogen atmosphere to obtain materials with different nitrogen content. Their topography.

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Nonlinear electrical properties of glass-ceramics nanocomposites containing ferroelectric nanocrystallites of Bi2VO5.5

Nonlinear A.C. impedance measurements were conducted in the 50BiV-50SrBAlO nanocomposite as a function of frequency, temperature and A.C. voltage. This material is ferroelectric below temperature of 730 K, and above 730 K is a good ion-conductor. For this nanocomposite a low A.C. voltage of 1 V rms is enough to observe high nonlinearities. The origin of these nonlinear effects depends on the temperature and frequency. In the high.

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Mixed ionic-electronic conductivity and structural properties of strontium-borate glass containing nanocrystallites of Bi2 VO5.5

Samples of strontium borate glass containing bismuth vanadate nanocrystallites were prepared. Nanocomposites containing up to 45mol% of the Bi2VO5.5 phase exhibit electrical properties closer to the strontium-borate glass than to the ferroelectric Bi2VO5.5 ceramic. The glass matrix still may contain some part of bismuth and vanadium ions even after crystallization process and there is too little of crystalline phase to observe.

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Polaron hopping conduction in manganese borosilicate glass

A study on a novel material – manganese borosilicate glass without alkali metals, was reported. It was found that the obtained samples containing high amount of manganese oxide (60MnO–xSiO2–(40 − x)B2O3, x = 5, 10, 15, 20 and 30 mol%) were amorphous and homogeneous. XPS measurements showed that most of manganese ions are at oxidation level of Mn2 + ions and the mean oxidation level slightly moves toward higher value, with increasing.

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Nanokompozyty – ceramiki ferroelektrycznej umieszczonej w matrycy szklanej, dzięki swoim interesującym właściwościom znajdują zastosowanie w wielu urządzeniach i elementach elektronicznych. Jednym z ciekawych ferroelektryków jest ceramika Bi2VO5,5, która wykazuje wysokie przewodnictwo jonowe i przenikalność dielektryczną oraz nieliniowe właściwości optyczne. Przykładem szkła, o strukturze umożliwiającej rozmieszczenie wewnątrz.

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Characterization of structural, thermal and mechanical properties of bismuth silicate glasses

he influence of heating and reduction processes on the structural, thermal and mechanical properties of bismuth-silicate glasses has been investigated. Two compositions of glasses: 40Bi2O3–60SiO2 (Bi0.57Si0.43Ox) and 27Bi2O3–73SiO2 (Bi0.43Si0.57Ox) were fabricated by a typical melt quenching technique. Then the reduction in hydrogen at 380 °C for 20, 42 or 67 h was performed. It was found that a 50 μm-thick layer was formed on.

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Electrical conductivity and relaxation processes in V2O5 nanorods prepared by sol–gel method
  • M. Prześniak-Welenc
  • N. Wójcik
  • A. Winiarski
  • M. Łapiński
  • B. Kościelska
  • R. Barczyński
  • M. Gazda
  • W. Sadowski

Properties of high purity V2O5 nanorods prepared by a sol – gel method are presented. The studied materials were characterized by: X-ray diffractometry (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The electrical impedance was measured as a function of temperature and frequency. The obtained results show that the electrical conductivity increases with increasing temperature. The d.c. conductivity.

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Electronic and ionic relaxations in strontium-borate glass and glass-ceramics containing bismuth and vanadium oxides

The topography, microstructure and electrical properties of strontium-borate glass and SBO glass containing bismuth and vanadium oxides, were studied. The structure was measured using X-ray diffraction (XRD), Energy Dispersive X-ray Spectrometer (EDS) and Scanning electron microscope (SEM) methods. The A.C. complex conductivity was investigated as a function of temperature and frequency. The influence of the quantity of bismuth.

Microstructure and electrical properties of manganese borosilicate glasses

The structure, optical and electrical properties of manganese borosilicate glasses of the composition xMnO–(80 − x)SiO 2 –20B 2 O 3 (x = 40, 50, and 60 mol%) were investigated. The dependence of the glass structure on its composition was discussed and related to electrical properties. A separation of two amorphous phases was observed. It was suggested that one phase is MnO-rich and the other is SiO 2 -rich. It was found that.

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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties

The nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac.

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Electrical properties and structure of lead-borate glass containing iron ions
  • N. Szreder
  • R. Barczyński
  • J. Karczewski
  • M. Gazda

Solid State Ionics – 2020

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Electrical properties and structure of lead-borate glass containing iron ions.

The ac and dc conductivity in iron–lead-borate glass samples was investigated in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by the means of atomic force microscopy (AFM) and the crystalline phases (if present) were identified by the means of X-ray diffractometry. Two types of ac electrical behaviour were observed. The first group of glass samples which.

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Electronic conductivity in the SiO2–PbO–Fe2O3 glass containing magnetic nanostructures
  • R. Barczyński
  • N. Szreder
  • J. Karczewski
  • M. Gazda

Solid State Ionics – 2020

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Electronic conductivity in the SiO2-PbO-Fe2O3 glass containing magnetic nanostructures

The linear impedance spectra of iron–silicate–lead glass samples were measured in the frequency range from 1 MHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by means of XRD and atomic force microscopy. Local electrical and magnetic properties of the samples were tested with the aid of electrostatic force microscopy (EFM) and magnetic force microscopy (MFM). The obtained results show.

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Impedance Studies of Phosphate-iron Glasses Containing Niobium and Titanium

The ac and dc conductivity in phosphate-iron-niobate glasses with addition of titanium oxide was investigated as a function of temperature and frequency with the use of impedance spectroscopy. The topography and microstructure of glasses were investigated by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and confocal microscopy methods. The obtained results show that all samples are amorphous but they.

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Microstructure and Dielectric Properties of Barium-vanadate Glasses

The ac and dc conductivity in barium-vanadate glasses was investigated as a function of temperature and frequency with the use of impedance spectroscopy. The topography and microstructure of glasses were investigated by the means of X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. The XRD results show that all samples are amorphous but microscopy investigation reveals that glasses with greater amount of V2O5.

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Nanostructure and dielectric behavior of vanadate glasses containing BaTiO3

The ac and dc electrical conductivity of barium titanate doped bismuth-vanadate as-quenched and heat-treated materials was measured in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K with the impedance spectroscopy method. The microstructure was investigated by means of XRD, scanning electron microscopy (SEM), atomic force microscopy (AFM) and confocal microscopy. The obtained results showed.

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Phase Separation and Electrical Properties of Manganese Borosilicate Glasses

The structure and electrical properties of manganese borosilicate glasses of a composition of xMnO-(0.8-x)SiO2-(0.2)B2O3 (x=0.4, 0.5 and 0.6 in mol) were investigated by impedance spectroscopy, SEM, XRD and confocal microscopy methods. The influence of composition on the glass structure and electrical properties was discussed. A separation of two amorphous phases was observed and it was concluded that one phase is SiO2-rich and.

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Synthesis, single crystal growth and properties of Sr 5 Pb 3 ZnO 12
  • M. Winiarski
  • N. Szreder
  • R. Barczyński
  • T. Klimczuk
  • N. Wójcik
  • T. Klimczuk

Journal of Alloys and Compounds – 2020

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Synthesis, single crystal growth and properties of Sr5Pb3ZnO12

Abstract The novel Sr5Pb3ZnO12 oxide was synthesized by the solid-state reaction method. The crystal structure was studied by means of the powder x-ray diffraction Rietveld method and was found to be similar to 3 other previously known Sr5Pb3MO12 compounds (M = Co, Ni, Cu). Crystals of several hundred microns in size of the new phase were grown in molten sodium chloride and imaged using confocal optical and scanning electron microscopy.

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Właściwości elektryczne szkieł żelazowo – boranowo – ołowiowych zostały zbadane za pomocą metody spektroskopii impedancyjnej. Mechanizm przewodnictwa w szkłach tlenkowych zawierających jony żelaza może być wywołany hoppingiem małych polaronów. Celem niniejszej pracy było bliższe określenie zachodzącego w nich mechanizmu przewodnictwa. Wytworzono szkła o składzie dobranym na podstawie ich zakresu szklenia: xFe2O3 – (100 – x)(B2O3.

Właściwości elektryczne szkło-ceramiki zawierającej ferroelektryczną fazę BiV

Kompozyty szklano – ceramiczne zawierające nanokryształy posiadają właściwości fizyczne, które nie są możliwe do uzyskania w innych materiałach. Dzięki możliwości wytworzenia szkło – ceramik posiadających kryształy o różnej wielkości (nano, mikro. ) i różnorodnego typu, można w istotny sposób kontrolować właściwości elektryczne takich materiałów. Stała dielektryczna faz ferroelektrycznych jest bardzo wrażliwa na zmiany rozmiarów.

Ferromagnetic nanocrystallites in the SiO2 – PbO – Fe2O3 glass system

The structure of 50% SiO2 – 35% PbO – 15% Fe2O3, 50% SiO2 – 30% PbO – 20% Fe2O3 and 50% SiO2 – 25% PbO – 25% Fe2O3 (in mol%) glass was investigated by the means of AFM microscopy and X-ray diffraction. Observation by the atomic force microscopy shows that each of prepared iron oxide glass doesn’t have homogeneous structure and some nanocrystallites were detected. Next, test with neodymium magnet found out strong magnetic properties.

Linear and nonlinear impedance in iron oxide glasses containing alkaline ions and alkali free

The linear and nonlinear impedance spectra of oxide glasses were measured in the frequency range of 1 mHz to 1 MHz and in the temperature range of 153K to 483K. Two groups of iron oxide glass samples were prepared, the first one containing alkaline ions and the second one without alkali. In the first group, compositions of glasses were as follows: (in %mol) 50% SiO2 , 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O.


Literatura opiusuje próby wytworzenia nanokompozytów, w których skład wchodzą matryca szkła i rozproszone w niej nanokrystality fazy ferroelektrycznej. Najczęstsza metoda wykorzystywana do otrzymywania takiej szkło – ceramiki polega na wytopie szkła, a następnie jego krystalizacji. W literaturze można znaleźć dużo przykładów wytwarzania tego typu materiałów dwu lub więcej składnikowych. Najwięcej badań dotyczy ferroelektrycznych.


Zbadano właściwości elektryczne szkieł krzemianowo – ołowiowo – żelazowych. Szkła tlenkowe zawierające jony żelaza mogą potencjalnie wykazywać przewodnictwo polaronowe. Celem niniejszej pracy było bliższe określenie zachodzącego w nich mechanizmu przewodnictwa. Wytworzono szkła o składzie dobranym na podstawie ich zakresu szklenia: (50 – 0.5x)[SiO2, PbO] – xFe2O3 gdzie x wynosił odpowiednio 2, 5, 10, 15, 20 i 25 (w % mol). Otrzymane.

SAT / ACT Prep Online Guides and Tips

The Complete IB Chemistry Syllabus: SL and HL

IB Chemistry is tough. If you are reading this syllabus, I assume you are interested in potentially taking this course or you are currently enrolled in the course. In this article, I’ll discuss every topic covered in IB Chemistry Standard Level and IB Chemistry Higher Level and the number of hours dedicated to each topic along with what the IB expects you to understand in each topic.

2020 IB Test Cancellation Due to COVID-19

Because of the COVID-19 (coronavirus) pandemic, IB exams for May 2020 have been canceled and coursework deadlines have been extended for schools that have closed. Stay up to date with the latest information on what this means for IB diplomas, course credit for IB classes, and more with our IB COVID-19 FAQ article.

IB Chemistry SL and HL Core

Both IB Chemistry SL and HL cover the first 11 topics (a total of 95 hours), and HL additionally covers topics 12 to 21 (an additional 60 hours). For both levels, you’ll also study one of the four options A-D (15 hours for SL, 25 hours for HL).

Topic #1: Stoichiometric Relationships—13.5 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Introduction to the particulate nature of matter and chemical change 1.1
  • „Atoms of different elements combine in fixed ratios to form compounds, which have different properties from their component elements.”
  • „Mixtures contain more than one element and/or compound that are not chemically bonded together and so retain their individual properties.”
  • „Mixtures are either homogeneous or heterogeneous.”
The mole concept 1.2
  • „The mole is a fixed number of particles and refers to the amount, n, of substance.”
  • „Masses of atoms are compared on a scale relative to 12C and are expressed as relative atomic mass (Ar) and relative formula/molecular mass (Mr).”
  • „Molar mass (M) has the units g mol-1.”
  • „The empirical formula and molecular formula of a compound give the simplest ratio and the actual number of atoms present in a molecule respectively.”
Reacting masses and volumes 1.3
  • „Reactants can be either limiting or excess.”
  • „The experimental yield can be different from the theoretical yield.”
  • „Avogadro’s law enables the mole ratio of reacting gases to be determined from volumes of the gases.”
  • „The molar volume of an ideal gas is a constant at specified temperature and pressure.”
  • „The molar concentration of a solution is determined by the amount of solute and the volume of solution.”
  • „A standard solution is one of known concentration.”

Topic #2: Atomic Structure—6 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
The nuclear atom 2.1
  • „Atoms contain a positively charged dense nucleus composed of protons and neutrons (nucleons).”
  • „Negatively charged electrons occupy the space outside the nucleus.”
  • „The mass spectrometer is used to determine the relative atomic mass of an element from its isotopic composition.”
Electron configuration 2.2
  • „Emission spectra are produced when photons are emitted from atoms as excited electrons return to a lower energy level.”
  • „The line emission spectrum of hydrogen provides evidence for the existence of electrons in discrete energy levels, which converge at higher energies.”
  • „The main energy level or shell is given an integer number, n, and can hold a maximum number of electrons, 2n2.”
  • „A more detailed model of the atom describes the division of the main energy level into s, p, d and f sub-levels of successively higher energies.”
  • „Sub-levels contain a fixed number of orbitals, regions of space where there is a high probability of finding an electron.”
  • „Each orbital has a defined energy state for a given electronic configuration and chemical environment and can hold two electrons of opposite spin.”

Topic #3: Periodicity—6 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Periodic table 3.1
  • „The periodic table is arranged into four blocks associated with the four sub- levels—s, p, d, and f.”
  • „The periodic table consists of groups (vertical columns) and periods (horizontal rows).”
  • „The period number (n) is the outer energy level that is occupied by electrons.”
  • „The number of the principal energy level and the number of the valence electrons in an atom can be deduced from its position on the periodic table.”
  • „The periodic table shows the positions of metals, non-metals and metalloids.”
Periodic trends 3.2
  • „Vertical and horizontal trends in the periodic table exist for atomic radius, ionic radius, ionization energy, electron affinity and electronegativity.”
  • „Trends in metallic and non-metallic behaviour are due to the trends above.”
  • „Oxides change from basic through amphoteric to acidic across a period.”

Topic #4: Chemical Bonding and Structure—13.5 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Ionic bonding and structure 4.1
  • „Positive ions (cations) form by metals losing valence electrons.”
  • „Negative ions (anions) form by non-metals gaining electrons.”
  • „The number of electrons lost or gained is determined by the electron configuration of the atom.”
  • „The ionic bond is due to electrostatic attraction between oppositely charged ions.”
  • „Under normal conditions, ionic compounds are usually solids with lattice structures.”
Covalent bonding 4.2
  • „A covalent bond is formed by the electrostatic attraction between a shared pair of electrons and the positively charged nuclei.”
  • „Single, double and triple covalent bonds involve one, two and three shared pairs of electrons respectively.”
  • „Bond length decreases and bond strength increases as the number of shared electrons increases.”
  • „Bond polarity results from the difference in electronegativities of the bonded atoms.”
Covalent structures 4.3
  • „Lewis (electron dot) structures show all the valence electrons in a covalently bonded species.”
  • „The „octet rule” refers to the tendency of atoms to gain a valence shell with a total of 8 electrons.”
  • „Some atoms, like Be and B, might form stable compounds with incomplete octets of electrons.”
  • „Resonance structures occur when there is more than one possible position for a double bond in a molecule.”
  • „Shapes of species are determined by the repulsion of electron pairs according to VSEPR theory.”
  • „Carbon and silicon form giant covalent/network covalent structures.”
Intermolecular forces 4.4
  • „Intermolecular forces include London (dispersion) forces, dipole-dipole forces and hydrogen bonding.”
  • „The relative strengths of these interactions are London (dispersion) forces

Topic #6: Chemical Kinetics—7 Hours for Both SL and HL

Subtopic Subtopic Number IB Points to Understand
Collision theory and rates of reaction 6.1
  • „Species react as a result of collisions of sufficient energy and proper orientation.”
  • „The rate of reaction is expressed as the change in concentration of a particular reactant/product per unit time.”
  • „Concentration changes in a reaction can be followed indirectly by monitoring changes in mass, volume and colour.”
  • „Activation energy (Ea) is the minimum energy that colliding molecules need in order to have successful collisions leading to a reaction.”
  • „By decreasing Ea, a catalyst increases the rate of a chemical reaction, without itself being permanently chemically changed.”

Topic #7: Equilibrium—4.5 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Equilibrium 7.1
  • „A state of equilibrium is reached in a closed system when the rates of the forward and reverse reactions are equal.”
  • „The equilibrium law describes how the equilibrium constant (Kc) can be determined for a particular chemical reaction.”
  • „The magnitude of the equilibrium constant indicates the extent of a reaction at equilibrium and is temperature dependent.”
  • „The reaction quotient (Q) measures the relative amount of products and reactants present during a reaction at a particular point in time. Q is the equilibrium expression with non-equilibrium concentrations. The position of the equilibrium changes with changes in concentration, pressure, and temperature.”
  • „A catalyst has no effect on the position of equilibrium or the equilibrium constant.”

Topic #8: Acids and Bases—6.5 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Theories of acids and bases 8.1
  • „A Brønsted–Lowry acid is a proton/H+ donor and a Brønsted–Lowry base is a proton/H+ acceptor.”
  • „Amphiprotic species can act as both Brønsted–Lowry acids and bases.”
  • „A pair of species differing by a single proton is called a conjugate acid-base pair.”
Properties of acids and bases 8.2
  • „Most acids have observable characteristic chemical reactions with reactive metals, metal oxides, metal hydroxides, hydrogen carbonates and carbonates.”
  • „Salt and water are produced in exothermic neutralization reactions.”
The pH scale 8.3
  • „pH = − log[H+(aq)] and [H+] = 10−pH.”
  • „A change of one pH unit represents a 10-fold change in the hydrogen ion concentration [����+].”
  • „pH values distinguish between acidic, neutral and alkaline solutions.”
  • „The ionic product constant, �������� = [H+][OH−] = 10−14 at 298 K.”
Strong and weak acids and bases 8.4
  • „Strong and weak acids and bases differ in the extent of ionization.”
  • „Strong acids and bases of equal concentrations have higher conductivities than weak acids and bases.”
  • „A strong acid is a good proton donor and has a weak conjugate base.”
  • „A strong base is a good proton acceptor and has a weak conjugate acid.”
Acid deposition 8.5
  • „Rain is naturally acidic because of dissolved CO2 and has a pH of 5.6. Acid deposition has a pH below 5.6.”
  • „Acid deposition is formed when nitrogen or sulfur oxides dissolve in water to form HNO3, HNO2, H2SO4 and H2SO3.”
  • „Sources of the oxides of sulfur and nitrogen and the effects of acid deposition should be covered.”

Topic #9: Redox Processes—8 Hours for SL and HL

Voltaic (Galvanic) cells

  • „Voltaic cells convert energy from spontaneous, exothermic chemical processes to electrical energy.”
  • „Oxidation occurs at the anode (negative electrode) and reduction occurs at the cathode (positive electrode) in a voltaic cell.”
  • „Electrolytic cells convert electrical energy to chemical energy, by bringing about non-spontaneous processes.”
  • „Oxidation occurs at the anode (positive electrode) and reduction occurs at the cathode (negative electrode) in an electrolytic cell.”
Subtopic Subtopic Number IB Points to Understand
Oxidation and reduction 9.1
  • „Oxidation and reduction can be considered in terms of oxygen gain/hydrogen loss, electron transfer or change in oxidation number.”
  • „An oxidizing agent is reduced and a reducing agent is oxidized.”
  • „Variable oxidation numbers exist for transition metals and for most main-group non-metals.”
  • „The activity series ranks metals according to the ease with which they undergo oxidation.”
  • „The Winkler Method can be used to measure biochemical oxygen demand (BOD), used as a measure of the degree of pollution in a water sample.”
Electrochemical cells 9.2

Topic #10: Organic Chemistry—11 Hours for SL and HL

  • „Alkanes have low reactivity and undergo free-radical substitution reactions.”
  • „Alkenes are more reactive than alkanes and undergo addition reactions. Bromine water can be used to distinguish between alkenes and alkanes.”

  • „Alcohols undergo nucleophilic substitution reactions with acids (also called esterification or condensation) and some undergo oxidation reactions.”
  • „Halogenoalkanes are more reactive than alkanes. They can undergo (nucleophilic) substitution reactions. A nucleophile is an electron-rich species containing a lone pair that it donates to an electron-deficient carbon.”
  • „Addition polymers consist of a wide range of monomers and form the basis of the plastics industry.”
  • „Benzene does not readily undergo addition reactions but does undergo electrophilic substitution reactions.”
Subtopic Subtopic Number IB Points to Understand
Fundamentals of organic chemistry 10.1
  • „A homologous series is a series of compounds of the same family, with the same general formula, which differ from each other by a common structural unit.”
  • „Structural formulas can be represented in full and condensed format.”
  • „Structural isomers are compounds with the same molecular formula but different arrangements of atoms.”
  • „Functional groups are the reactive parts of molecules.”
  • „Saturated compounds contain single bonds only and unsaturated compounds contain double or triple bonds.”
  • „Benzene is an aromatic, unsaturated hydrocarbon.”
Functional group chemistry 10.2

Topic #11: Measurement and Data Processing—10 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Uncertainties and errors in measurement and results 11.1
  • „Qualitative data includes all non-numerical information obtained from observations not from measurement.”
  • „Quantitative data are obtained from measurements, and are always associated with random errors/uncertainties, determined by the apparatus, and by human limitations such as reaction times.”
  • „Propagation of random errors in data processing shows the impact of the uncertainties on the final result.”
  • „Experimental design and procedure usually lead to systematic errors in measurement, which cause a deviation in a particular direction.”
  • „Repeat trials and measurements will reduce random errors but not systematic errors.”
Graphical techniques 11.2
  • „Graphical techniques are an effective means of communicating the effect of an independent variable on a dependent variable, and can lead to determination of physical quantities.”
  • „Sketched graphs have labeled but unscaled axes, and are used to show qualitative trends, such as variables that are proportional or inversely proportional.”
  • „Drawn graphs have labeled and scaled axes, and are used in quantitative measurements.”
Spectroscopic identification of organic compounds 11.3
  • „The degree of unsaturation or index of hydrogen deficiency (IHD) can be used to determine from a molecular formula the number of rings or multiple bonds in a molecule.”
  • „Mass spectrometry (MS), proton nuclear magnetic resonance spectroscopy (1H NMR) and infrared spectroscopy (IR) are techniques that can be used to help identify compounds and to determine their structure.”

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Additional Higher Level Topics

These topics (a total of 60 hours) are only for Higher Level students.

Topic #12: Atomic Structure—2 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Electrons in atoms
  • „In an emission spectrum, the limit of convergence at higher frequency corresponds to the first ionization energy.”
  • „Trends in first ionization energy across periods account for the existence of main energy levels and sub-levels in atoms.”
  • „Successive ionization energy data for an element give information that shows relations to electron configurations.”

Topic #13: The Periodic Table: Transition Metals—4 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
First-row d-block elements
  • „Transition elements have variable oxidation states, form complex ions with ligands, have coloured compounds, and display catalytic and magnetic properties.”
  • „Zn is not considered to be a transition element as it does not form ions with incomplete d-orbitals.”
  • „Transition elements show an oxidation state of +2 when the s-electrons are removed.”
Coloured complexes
  • „The d sub-level splits into two sets of orbitals of different energy in a complex ion.”
  • „Complexes of d-block elements are coloured, as light is absorbed when an electron is excited between the d-orbitals.”
  • „The colour absorbed is complementary to the colour observed.”

Topic #14: Chemical Bonding and Structure—7 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Further aspects of covalent bonding and structure
  • „Covalent bonds result from the overlap of atomic orbitals. A sigma bond (σ) is formed by the direct head-on/end-to-end overlap of atomic orbitals, resulting in electron density concentrated between the nuclei of the bonding atoms. A pi bond (π) is formed by the sideways overlap of atomic orbitals, resulting in electron density above and below the plane of the nuclei of the bonding atoms.”
  • „Formal charge (FC) can be used to decide which Lewis (electron dot) structure is preferred from several. The FC is the charge an atom would have if all atoms in the molecule had the same electronegativity. FC = (Number of valence electrons)-½(Number of bonding electrons)-(Number of non-bonding electrons). The Lewis (electron dot) structure with the atoms having FC values closest to zero is preferred.”
  • „Exceptions to the octet rule include some species having incomplete octets and expanded octets.”
  • „Delocalization involves electrons that are shared by/between all atoms in a molecule or ion as opposed to being localized between a pair of atoms.”
  • „Resonance involves using two or more Lewis (electron dot) structures to represent a particular molecule or ion. A resonance structure is one of two or more alternative Lewis (electron dot) structures for a molecule or ion that cannot be described fully with one Lewis (electron dot) structure alone.”
  • „A hybrid orbital results from the mixing of different types of atomic orbitals on the same atom.”

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Topic #15: Energetics/Thermochemistry—7 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Energy cycles
  • „Representative equations (eg M +(g) → M +(aq) ) can be used for enthalpy/energy of hydration, ionization, atomization, electron affinity, lattice, covalent bond and solution.”
  • „Enthalpy of solution, hydration enthalpy and lattice enthalpy are related in an energy cycle.”
Entropy and spontaneity
  • „Entropy (S) refers to the distribution of available energy among the particles. The more ways the energy can be distributed the higher the entropy.”
  • „Gibbs free energy (G) relates the energy that can be obtained from a chemical reaction to the change in enthalpy (ΔH), change in entropy (ΔS), and absolute temperature (T).”
  • „Entropy of gas>liquid>solid under same conditions.”

Topic #16: Chemical Kinetics—6 Hours for HL Only

Activation energy

Subtopic Subtopic Number IB Points to Understand
Rate expression and reaction mechanism
  • „Reactions may occur by more than one step and the slowest step determines the rate of reaction (rate determining step/RDS).”
  • „The molecularity of an elementary step is the number of reactant particles taking part in that step.”
  • „The order of a reaction can be either integer or fractional in nature. The order of a reaction can describe, with respect to a reactant, the number of particles taking part in the rate-determining step.”
  • „Rate equations can only be determined experimentally.”
  • „The value of the rate constant (k) is affected by temperature and its units are determined from the overall order of the reaction.”
  • „Catalysts alter a reaction mechanism, introducing a step with lower activation energy.”
  • „The Arrhenius equation uses the temperature dependence of the rate constant to determine the activation energy.”
  • „A graph of 1/T against ln k is a linear plot with gradient – Ea / R and intercept, lnA.”
  • „The frequency factor (or pre-exponential factor) (A) takes into account the frequency of collisions with proper orientations.”

Topic #17: Equilibrium—4 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
The equilibrium law
  • „Le Châtelier’s principle for changes in concentration can be explained by the equilibrium law.”
  • „The position of equilibrium corresponds to a maximum value of entropy and a minimum in the value of the Gibbs free energy.”
  • „The Gibbs free energy change of a reaction and the equilibrium constant can both be used to measure the position of an equilibrium reaction and are related by the equation, ∆G° = −RT ln(��)”

Topic #18: Acids and Bases—10 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Lewis acids and bases
  • „A Lewis acid is a lone pair acceptor and a Lewis base is a lone pair donor.”
  • „When a Lewis base reacts with a Lewis acid a coordinate bond is formed.”
  • „A nucleophile is a Lewis base and an electrophile is a Lewis acid.”
Calculations involving acids and bases
  • „The expression for the dissociation constant of a weak acid (Ka) and a weak base (Kb).”
  • „For a conjugate acid base pair, Ka × Kb = Kw.”
  • „The relationship between Ka and pKa is (pKa = -log Ka), and between Kb and pKb is (pKb = -log Kb).”
pH curves
  • „The characteristics of the pH curves produced by the different combinations of strong and weak acids and bases.”
  • „An acid–base indicator is a weak acid or a weak base where the components of the conjugate acid–base pair have different colours.”
  • „The relationship between the pH range of an acid–base indicator, which is a weak acid, and its pKa value.”
  • „The buffer region on the pH curve represents the region where small additions of acid or base result in little or no change in pH.”
  • „The composition and action of a buffer solution.”

Topic #19: Redox Processes—6 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Electrochemical cells
  • „A voltaic cell generates an electromotive force (EMF) resulting in the movement of electrons from the anode (negative electrode) to the cathode (positive electrode) via the external circuit. The EMF is termed the cell potential (Eº).”
  • „The standard hydrogen electrode (SHE) consists of an inert platinum electrode in contact with 1 mol dm-3 hydrogen ion and hydrogen gas at 100 kPa and 298 K. The standard electrode potential (Eº) is the potential (voltage) of the reduction half-equation under standard conditions measured relative to the SHE. Solute concentration is 1 mol dm-3 or 100 kPa for gases. Eº of the SHE is 0 V.”
  • „When aqueous solutions are electrolysed, water can be oxidized to oxygen at the anode and reduced to hydrogen at the cathode.
  • „ΔGº = –nFEº. When Eº is positive, ΔGº is negative indicative of a spontaneous process. When Eº is negative, ΔGº is positive indicative of a non-spontaneous process. When Eº is 0, then ΔGº is 0.”
  • „Current, duration of electrolysis and charge on the ion affect the amount of product formed at the electrodes during electrolysis.”
  • „Electroplating involves the electrolytic coating of an object with a metallic thin layer.”

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Topic #20: Organic Chemistry—12 Hours for HL Only

Nucleophilic Substitution Reactions:

  • „SN1 represents a nucleophilic unimolecular substitution reaction and SN2 represents a nucleophilic bimolecular substitution reaction. SN1 involves a carbocation intermediate. SN2 involves a concerted reaction with a transition state.”
  • „For tertiary halogenoalkanes the predominant mechanism is SN1 and for primary halogenoalkanes it is SN2. Both mechanisms occur for secondary halogenoalkanes.”
  • „The rate determining step (slow step) in an SN1 reaction depends only on the concentration of the halogenoalkane, rate = k[halogenoalkane]. For SN2, rate = k[halogenoalkane][nucleophile]. SN2 is stereospecific with an inversion of configuration at the carbon.”
  • „SN2 reactions are best conducted using aprotic, non-polar solvents and SN1 reactions are best conducted using protic, polar solvents.”

Electrophilic Addition Reactions:

  • „An electrophile is an electron-deficient species that can accept electron pairs from a nucleophile. Electrophiles are Lewis acids.”
  • „Markovnikov’s rule can be applied to predict the major product in electrophilic addition reactions of unsymmetrical alkenes with hydrogen halides and interhalogens. The formation of the major product can be explained in terms of the relative stability of possible carbocations in the reaction mechanism.”

Electrophilic Substitution Reactions:

  • „Benzene is the simplest aromatic hydrocarbon compound (or arene) and has a delocalized structure of π bonds around its ring. Each carbon to carbon bond has a bond order of 1.5. Benzene is susceptible to attack by electrophiles.”
  • „Carboxylic acids can be reduced to primary alcohols (via the aldehyde). Ketones can be reduced to secondary alcohols. Typical reducing agents are lithium aluminium hydride (used to reduce carboxylic acids) and sodium borohydride.”
Subtopic Subtopic Number IB Points to Understand
Types of organic reactions
Synthetic routes
  • „The synthesis of an organic compound stems from a readily available starting material via a series of discrete steps. Functional group interconversions are the basis of such synthetic routes.”
  • „Retro-synthesis of organic compounds.”
  • „Stereoisomers are subdivided into two classes—conformational isomers, which interconvert by rotation about a σ bond and configurational isomers that interconvert only by breaking and reforming a bond. Configurational isomers are further subdivided into cis-trans and E/Z isomers and optical isomers.”
  • „Cis-trans isomers can occur in alkenes or cycloalkanes (or heteroanalogues) and differ in the positions of atoms (or groups) relative to a reference plane. According to IUPAC, E/Z isomers refer to alkenes of the form R1R2C=CR3R4 (R1 ≠ R2, R3 ≠ R4) where neither R1 nor R2 need be different from R3 or R4.”
  • „A chiral carbon is a carbon joined to four different atoms or groups.”
  • „An optically active compound can rotate the plane of polarized light as it passes through a solution of the compound. Optical isomers are enantiomers. Enantiomers are non-superimposeable mirror images of each other. Diastereomers are not mirror images of each other.”
  • „A racemic mixture (or racemate) is a mixture of two enantiomers in equal amounts and is optically inactive.”

Topic #21: Measurement and Analysis—2 Hours for HL Only

Subtopic Subtopic Number IB Points to Understand
Spectroscopic identification of organic compounds
  • „Structural identification of compounds involves several different analytical techniques including IR, 1H NMR and MS.”
  • „In a high resolution 1H NMR spectrum, single peaks present in low resolution can split into further clusters of peaks.”
  • „The structural technique of single crystal X-ray crystallography can be used to identify the bond lengths and bond angles of crystalline compounds.”


As a part of your IB Chemistry class you’ll cover an additional subject from the list below (typically your teacher chooses which subject you’ll cover). Whichever option is chosen, you’ll cover 5-7 topics (15 hours total) for SL and an additional 3 or 4 topics (25 hours total) for HL.

Option A: Materials—15 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Materials science introduction A.1
  • „Materials are classified based on their uses, properties, or bonding and structure.”
  • „The properties of a material based on the degree of covalent, ionic or metallic character in a compound can be deduced from its position on a bonding triangle.”
  • „Composites are mixtures in which materials are composed of two distinct phases, a reinforcing phase that is embedded in a matrix phase.”
Metals and inductively coupled plasma (ICP) spectroscopy A.2
  • „Reduction by coke (carbon), a more reactive metal, or electrolysis are means of obtaining some metals from their ores.”
  • „The relationship between charge and the number of moles of electrons is given by Faraday’s constant, F.
  • „Alloys are homogeneous mixtures of metals with other metals or non-metals.”
  • „Diamagnetic and paramagnetic compounds differ in electron spin pairing and their behaviour in magnetic fields.”
  • „Trace amounts of metals can be identified and quantified by ionizing them with argon gas plasma in Inductively Coupled Plasma (ICP) Spectroscopy using Mass Spectroscopy ICP-MS and Optical Emission Spectroscopy ICP-OES.”
Catalysts A.3
  • „Reactants adsorb onto heterogeneous catalysts at active sites and the products desorb.”
  • „Homogeneous catalysts chemically combine with the reactants to form a temporary activated complex or a reaction intermediate.”
  • „Transition metal catalytic properties depend on the adsorption/absorption properties of the metal and the variable oxidation states.”
  • „Zeolites act as selective catalysts because of their cage structure.”
  • „Catalytic particles are nearly always nanoparticles that have large surface areas per unit mass.”
Liquid crystals A.4
  • „Liquid crystals are fluids that have physical properties (electrical, optical and elasticity) that are dependent on molecular orientation to some fixed axis in the material.”
  • „Thermotropic liquid-crystal materials are pure substances that show liquidcrystal behaviour over a temperature range.”
  • „Lyotropic liquid crystals are solutions that show the liquid-crystal state over a (certain) range of concentrations.”
  • „Nematic liquid crystal phase is characterized by rod shaped molecules which are randomly distributed but on average align in the same direction.”
Polymers A.5
  • „Thermoplastics soften when heated and harden when cooled.”
  • „A thermosetting polymer is a prepolymer in a soft solid or viscous state that changes irreversibly into a hardened thermoset by curing.”
  • „Elastomers are flexible and can be deformed under force but will return to nearly their original shape once the stress is released.”
  • „High density polyethene (HDPE) has no branching allowing chains to be packed together.”
  • „Low density polyethene (LDPE) has some branching and is more flexible.”
  • „Plasticizers added to a polymer increase the flexibility by weakening the intermolecular forces between the polymer chains.”
  • „Atom economy is a measure of efficiency applied in green chemistry.”
  • „Isotactic addition polymers have substituents on the same side.”
  • „Atactic addition polymers have the substituents randomly placed.”
Nanotechnology A.6
  • „Molecular self-assembly is the bottom-up assembly of nanoparticles and can occur by selectively attaching molecules to specific surfaces. Self-assembly can also occur spontaneously in solution.”
  • „Possible methods of producing nanotubes are arc discharge, chemical vapour deposition (CVD) and high pressure carbon monoxide (HIPCO).”
  • „Arc discharge involves either vaporizing the surface of one of the carbon electrodes, or discharging an arc through metal electrodes submersed in a hydrocarbon solvent, which forms a small rod-shaped deposit on the anode.”
Environmental impact—plastics A.7
  • „Plastics do not degrade easily because of their strong covalent bonds.”
  • „Burning of polyvinyl chloride releases dioxins, HCl gas and incomplete hydrocarbon combustion products.”
  • „Dioxins contain unsaturated six-member heterocyclic rings with two oxygen atoms, usually in positions 1 and 4.”
  • „Chlorinated dioxins are hormone disrupting, leading to cellular and genetic damage.”
  • „Plastics require more processing to be recycled than other materials.”
  • „Plastics are recycled based on different resin types.”

Option A: Additional HL Materials Topics—10 More Hours for HL

Subtopic Subtopic Number IB Points to Understand
Superconducting metals and X-ray crystallography
  • „Superconductors are materials that offer no resistance to electric currents below a critical temperature.”
  • „The Meissner effect is the ability of a superconductor to create a mirror image magnetic field of an external field, thus expelling it.”
  • „Resistance in metallic conductors is caused by collisions between electrons and positive ions of the lattice.”
  • „The Bardeen–Cooper–Schrieffer (BCS) theory explains that below the critical temperature electrons in superconductors form Cooper pairs which move freely through the superconductor.”
  • „Type 1 superconductors have sharp transitions to superconductivity whereas Type 2 superconductors have more gradual transitions.”
  • „X-ray diffraction can be used to analyse structures of metallic and ionic compounds.”
  • „Crystal lattices contain simple repeating unit cells.”
  • „Atoms on faces and edges of unit cells are shared.”
  • „The number of nearest neighbours of an atom/ion is its coordination number.”
Condensation polymers
  • „Condensation polymers require two functional groups on each monomer.”
  • „NH3, HCl and H2O are possible products of condensation reactions.”
  • „Kevlar® is a polyamide with a strong and ordered structure. The hydrogen bonds between O and N can be broken with the use of concentrated sulfuric acid.”
Environmental impact—heavy metals
  • „Toxic doses of transition metals can disturb the normal oxidation/reduction balance in cells through various mechanisms.”
  • „Some methods of removing heavy metals are precipitation, adsorption, and chelation.”
  • „Polydentate ligands form more stable complexes than similar monodentate ligands due to the chelate effect, which can be explained by considering entropy changes.”

Option B: Biochemistry—15 Hours for SL and HL

Subtopic Subtopic Number IB Points to Understand
Introduction to biochemistry B.1
  • „The diverse functions of biological molecules depend on their structures and shapes.”
  • „Metabolic reactions take place in highly controlled aqueous environments.”
  • „Reactions of breakdown are called catabolism and reactions of synthesis are called anabolism.”
  • „Biopolymers form by condensation reactions and are broken down by hydrolysis reactions.”
  • „Photosynthesis is the synthesis of energy-rich molecules from carbon dioxide and water using light energy.”
  • „Respiration is a complex set of metabolic processes providing energy for cells.”
Proteins and enzymes B.2
  • „Proteins are polymers of 2-amino acids, joined by amide links (also known as peptide bonds).”
  • „Amino acids are amphoteric and can exist as zwitterions, cations and anions.”
  • „Protein structures are diverse and are described at the primary, secondary, tertiary and quaternary levels.”
  • „A protein’s three-dimensional shape determines its role in structural components or in metabolic processes.”
  • „Most enzymes are proteins that act as catalysts by binding specifically to a substrate at the active site.”
  • „As enzyme activity depends on the conformation, it is sensitive to changes in temperature and pH and the presence of heavy metal ions.”
  • „Chromatography separation is based on different physical and chemical principles.”
Lipids B.3
  • „Fats are more reduced than carbohydrates and so yield more energy when oxidized.”
  • „Triglycerides are produced by condensation of glycerol with three fatty acids and contain ester links. Fatty acids can be saturated, monounsaturated or polyunsaturated.”
  • „Phospholipids are derivatives of triglycerides.”
  • „Hydrolysis of triglycerides and phospholipids can occur using enzymes or in alkaline or acidic conditions.”
  • „Steroids have a characteristic fused ring structure, known as a steroidal backbone.”
  • „Lipids act as structural components of cell membranes, in energy storage, thermal and electrical insulation, as transporters of lipid soluble vitamins and as hormones.”
Carbohydrates B.4
  • „Carbohydrates have the general formula Cx(H2O)y.”
  • „Haworth projections represent the cyclic structures of monosaccharides.”
  • „Monosaccharides contain either an aldehyde group (aldose) or a ketone group (ketose) and several –OH groups.”
  • „Straight chain forms of sugars cyclize in solution to form ring structures containing an ether linkage.”
  • „Glycosidic bonds form between monosaccharides forming disaccharides and polysaccharides.”
  • „Carbohydrates are used as energy sources and energy reserves.”
Vitamins B.5
  • „Vitamins are organic micronutrients which (mostly) cannot be synthesized by the body but must be obtained from suitable food sources.”
  • „The solubility (water or fat) of a vitamin can be predicted from its structure.”
  • „Most vitamins are sensitive to heat.”
  • „Vitamin deficiencies in the diet cause particular diseases and affect millions of people worldwide.”
Biochemistry and the environment B.6
  • „Xenobiotics refer to chemicals that are found in an organism that are not normally present there.”
  • „Biodegradable/compostable plastics can be consumed or broken down by bacteria or other living organisms.”
  • „Host–guest chemistry involves the creation of synthetic host molecules that mimic some of the actions performed by enzymes in cells, by selectively binding to specific guest species, such as toxic materials in the environment.”
  • „Enzymes have been developed to help in the breakdown of oil spills and other industrial wastes.”
  • „Enzymes in biological detergents can improve energy efficiency by enabling effective cleaning at lower temperatures.”
  • „Biomagnification is the increase in concentration of a substance in a food chain.”
  • „Green chemistry, also called sustainable chemistry, is an approach to chemical research and engineering that seeks to minimize the production and release to the environment of hazardous substances.”

Option B: Additional HL Biochemistry Topics—10 More Hours for HL

Subtopic Subtopic Number IB Points to Understand
Proteins and enzymes
  • „Inhibitors play an important role in regulating the activities of enzymes.”
  • „Amino acids and proteins can act as buffers in solution.”
  • „Protein assays commonly use UV-vis spectroscopy and a calibration curve based on known standards.”
Nucleic acids
  • „Nucleotides are the condensation products of a pentose sugar, phosphoric acid and a nitrogenous base—adenine (A), guanine (G), cytosine (C), thymine (T) or uracil (U).”
  • „Polynucleotides form by condensation reactions.”
  • „DNA is a double helix of two polynucleotide strands held together by hydrogen bonds.”
  • „RNA is usually a single polynucleotide chain that contains uracil in place of thymine, and a sugar ribose in place of deoxyribose.”
  • „The sequence of bases in DNA determines the primary structure of proteins synthesized by the cell using a triplet code, known as the genetic code, which is universal.”
  • „Genetically modified organisms have genetic material that has been altered by genetic engineering techniques, involving transferring DNA between species.”
Biological pigments
  • „Biological pigments are coloured compounds produced by metabolism.”
  • „The colour of pigments is due to highly conjugated systems with delocalized electrons, which have intense absorption bands in the visible region.”
  • „Porphyrin compounds, such as hemoglobin, myoglobin, chlorophyll and many cytochromes are chelates of metals with large nitrogen-containing macrocyclic ligands.”
  • „Hemoglobin and myoglobin contain heme groups with the porphyrin group bound to an iron(II) ion.”
  • „Cytochromes contain heme groups in which the iron ion interconverts between iron(II) and iron(III) during redox reactions.”
  • „Anthocyanins are aromatic, water-soluble pigments widely distributed in plants. Their specific colour depends on metal ions and pH.”
  • „Carotenoids are lipid-soluble pigments, and are involved in harvesting light in photosynthesis. They are susceptible to oxidation, catalysed by light.”
Stereochemistry in biomolecules
  • „With one exception, amino acids are chiral, and only the L-configuration is found in proteins.”
  • „Naturally occurring unsaturated fat is mostly in the cis form, but food processing can convert it into the trans form.”
  • „D and L stereoisomers of sugars refer to the configuration of the chiral carbon atom furthest from the aldehyde or ketone group, and D forms occur most frequently in nature.”
  • „Ring forms of sugars have isomers, known as α and β, depending on whether the position of the hydroxyl group at carbon 1 (glucose) or carbon 2 (fructose) lies below the plane of the ring (α) or above the plane of the ring (β).”
  • „Vision chemistry involves the light activated interconversion of cis- and trans- isomers of retinal.”

Option C: Energy—15 Hours for SL and HL

  • „Light nuclei can undergo fusion reactions as this increases the binding energy per nucleon.”
  • „Fusion reactions are a promising energy source as the fuel is inexpensive and abundant, and no radioactive waste is produced.”
  • „Absorption spectra are used to analyse the composition of stars.”
  • „Heavy nuclei can undergo fission reactions as this increases the binding energy per nucleon.”
  • „235U undergoes a fission chain reaction: U235 92 + n10 → U 236 92 → X + Y + neutrons.”
  • „The critical mass is the mass of fuel needed for the reaction to be self-sustaining.”
  • „239Pu, used as a fuel in „breeder reactors”, is produced from 238U by neutron capture.”
  • „Radioactive waste may contain isotopes with long and short half-lives.”
  • „Half-life is the time it takes for half the number of atoms to decay.”
Subtopic Subtopic Number IB Points to Understand
Energy sources C.1
  • „A useful energy source releases energy at a reasonable rate and produces minimal pollution.”
  • „The quality of energy is degraded as heat is transferred to the surroundings. Energy and materials go from a concentrated into a dispersed form. The quantity of the energy available for doing work decreases.”
  • „Renewable energy sources are naturally replenished. Non-renewable energy sources are finite.”
  • „Energy density = energy released from fuel volume of fuel consumed.”
  • „Specific energy = energy released from fuel mass of fuel consumed.”
  • „The effeciency of an energy transfer = useful output energy total input energy x 100%.”
Fossil fuels C.2
  • „Fossil fuels were formed by the reduction of biological compounds that contain carbon, hydrogen, nitrogen, sulfur and oxygen.”
  • „Petroleum is a complex mixture of hydrocarbons that can be split into different component parts called fractions by fractional distillation.”
  • „Crude oil needs to be refined before use. The different fractions are separated by a physical process in fractional distillation.”
  • „The tendency of a fuel to auto-ignite, which leads to „knocking” in a car engine, is related to molecular structure and measured by the octane number.”
  • „The performance of hydrocarbons as fuels is improved by the cracking and catalytic reforming reactions.”
  • „Coal gasification and liquefaction are chemical processes that convert coal to gaseous and liquid hydrocarbons.”
  • „A carbon footprint is the total amount of greenhouse gases produced during human activities. It is generally expressed in equivalent tons of carbon dioxide.”
Nuclear fusion and fission C.3
Solar energy C.4
  • „Light can be absorbed by chlorophyll and other pigments with a conjugated electronic structure.”
  • „Photosynthesis converts light energy into chemical energy: 6CO2 + 6H2O ==> C6H12O6 + 6O2”
  • „Fermentation of glucose produces ethanol which can be used as a biofuel: C6H12O6 ==> 2C2H5OH + 2CO2.”
  • „Energy content of vegetable oils is similar to that of diesel fuel but they are not used in internal combustion engines as they are too viscous.”
  • „Transesterification between an ester and an alcohol with a strong acid or base catalyst produces a different ester: RCOOR1 + R2OH ==> RCOOR2 + R1OH.”
  • „In the transesterification process, involving a reaction with an alcohol in the presence of a strong acid or base, the triglyceride vegetable oils are converted to a mixture mainly comprising of alkyl esters and glycerol, but with some fatty acids.”
  • „Transesterification with ethanol or methanol produces oils with lower viscosity that can be used in diesel engines.”
Environmental impact—global warming C.5
  • „Greenhouse gases allow the passage of incoming solar short wavelength radiation but absorb the longer wavelength radiation from the Earth. Some of the absorbed radiation is re-radiated back to Earth.”
  • „There is a heterogeneous equilibrium between concentration of atmospheric carbon dioxide and aqueous carbon dioxide in the oceans.”
  • „Greenhouse gases absorb IR radiation as there is a change in dipole moment as the bonds in the molecule stretch and bend.”
  • „Particulates such as smoke and dust cause global dimming as they reflect sunlight, as do clouds.”

Option C: Additional HL Energy Topics—10 More Hours for HL

  • „The mass defect (∆m) is the difference between the mass of the nucleus and the sum of the masses of its individual nucleons.”
  • „The nuclear binding energy (ΔE) is the energy required to separate a nucleus into protons and neutrons.”
  • „The energy produced in a fission reaction can be calculated from the mass difference between the products and reactants using the Einstein mass–energy equivalence relationship �� = ��c^2.”
  • „The different isotopes of uranium in uranium hexafluoride can be separated, using diffusion or centrifugation causing fuel enrichment.”
  • „The effusion rate of a gas is inversely proportional to the square root of the molar mass (Graham’s Law).”
  • „Radioactive decay is kinetically a first order process with the half-life related to the decay constant by the equation �� = ln 2 /��1 .”
  • „The dangers of nuclear energy are due to the ionizing nature of the radiation it produces which leads to the production of oxygen free radicals such as superoxide (O2-), and hydroxyl (HO·). These free radicals can initiate chain reactions that can damage DNA and enzymes in living cells.”
Subtopic Subtopic Number IB Points to Understand
Electrochemistry, rechargeable batteries and fuel cells
  • „An electrochemical cell has internal resistance due to the finite time it takes for ions to diffuse. The maximum current of a cell is limited by its internal resistance.”
  • „The voltage of a battery depends primarily on the nature of the materials used while the total work that can be obtained from it depends on their quantity.”
  • „In a primary cell the electrochemical reaction is not reversible. Rechargeable cells involve redox reactions that can be reversed using electricity.”
  • „A fuel cell can be used to convert chemical energy, contained in a fuel that is consumed, directly to electrical energy.”
  • „Microbial fuel cells (MFCs) are a possible sustainable energy source using different carbohydrates or substrates present in waste waters as the fuel.”
  • „The Nernst equation can be used to calculate the potential of a half-cell in an electrochemical cell, under non-standard conditions.”
  • „The electrodes in a concentration cell are the same but the concentration of the electrolyte solutions at the cathode and anode are different.”
Nuclear fusion and nuclear fission
Photovoltaic cells and dye-sensitized solar cells (DSSC)
  • „Molecules with longer conjugated systems absorb light of longer wavelength.”
  • „The electrical conductivity of a semiconductor increases with an increase in temperature whereas the conductivity of metals decreases.”
  • „The conductivity of silicon can be increased by doping to produce n-type and p- type semiconductors.”
  • „Solar energy can be converted to electricity in a photovoltaic cell.”
  • „DSSCs imitate the way in which plants harness solar energy. Electrons are „injected” from an excited molecule directly into the TiO2 semiconductor.”
  • „The use of nanoparticles coated with light-absorbing dye increases the effective surface area and allows more light over a wider range of the visible spectrum to be absorbed.”

Option D: Medicinal Chemistry—15 Hours for SL and HL

  • „Mild analgesics function by intercepting the pain stimulus at the source, often by interfering with the production of substances that cause pain, swelling or fever.”
  • „Aspirin is prepared from salicylic acid.”
  • „Aspirin can be used as an anticoagulant, in prevention of the recurrence of heart attacks and strokes and as a prophylactic.”
  • „Penicillins are antibiotics produced by fungi.”
  • „A beta-lactam ring is a part of the core structure of penicillins.”
  • „Some antibiotics work by preventing cross-linking of the bacterial cell walls.”
  • „Modifying the side-chain results in penicillins that are more resistant to the penicillinase enzyme.”
Subtopic Subtopic Number IB Points to Understand
Pharmaceutical products and drug action D.1
  • „In animal studies, the therapeutic index is the lethal dose of a drug for 50% of the population (LD50) divided by the minimum effective dose for 50% of the population (ED50).”
  • „In humans, the therapeutic index is the toxic dose of a drug for 50% of the population (TD50) divided by the minimum effective dose for 50% of the population (ED50).”
  • „The therapeutic window is the range of dosages between the minimum amounts of the drug that produce the desired effect and a medically unacceptable adverse effect.”
  • „Dosage, tolerance, addiction and side effects are considerations of drug administration.”
  • „Bioavailability is the fraction of the administered dosage that reaches the target part of the human body.”
  • „The main steps in the development of synthetic drugs include identifying the need and structure, synthesis, yield and extraction.”
  • „Drug–receptor interactions are based on the structure of the drug and the site of activity.”
Aspirin and penicillin D.2
Opiates D.3
  • „The ability of a drug to cross the blood–brain barrier depends on its chemical structure and solubility in water and lipids.”
  • „Opiates are natural narcotic analgesics that are derived from the opium poppy.”
  • „Morphine and codeine are used as strong analgesics. Strong analgesics work by temporarily bonding to receptor sites in the brain, preventing the transmission of pain impulses without depressing the central nervous system.”
  • „Medical use and addictive properties of opiate compounds are related to the presence of opioid receptors in the brain.”
pH regulation of the stomach D.4
  • „Non-specific reactions, such as the use of antacids, are those that work to reduce the excess stomach acid.”
  • „Active metabolites are the active forms of a drug after it has been processed by the body.”
Antiviral medications D.5
  • „Viruses lack a cell structure and so are more difficult to target with drugs than bacteria.”
  • „Antiviral drugs may work by altering the cell’s genetic material so that the virus cannot use it to multiply. Alternatively, they may prevent the viruses from multiplying by blocking enzyme activity within the host cell.”
Environmental impact of some medications D.6
  • „High-level waste (HLW) is waste that gives off large amounts of ionizing radiation for a long time.”
  • „Low-level waste (LLW) is waste that gives off small amounts of ionizing radiation for a short time.”
  • „Antibiotic resistance occurs when micro-organisms become resistant to antibacterials.”

Option D: Additional HL Medicinal Chemistry Topics—10 More Hours for HL

Subtopic Subtopic Number IB Points to Understand
Taxol—a chiral auxiliary case study
  • „Taxol is a drug that is commonly used to treat several different forms of cancer.”
  • „Taxol naturally occurs in yew trees but is now commonly synthetically produced.”
  • „A chiral auxiliary is an optically active substance that is temporarily incorporated into an organic synthesis so that it can be carried out asymmetrically with the selective formation of a single enantiomer.”
Nuclear medicine
  • „Alpha, beta, gamma, proton, neutron and positron emissions are all used for medical treatment.”
  • „Magnetic resonance imaging (MRI) is an application of NMR technology.”
  • „Radiotherapy can be internal and/or external.”
  • „Targeted Alpha Therapy (TAT) and Boron Neutron Capture Therapy (BNCT) are two methods which are used in cancer treatment.”
Drug detection and analysis
  • „Organic structures can be analysed and identified through the use of infrared spectroscopy, mass spectroscopy and proton NMR.”
  • „The presence of alcohol in a sample of breath can be detected through the use of either a redox reaction or a fuel cell type of breathalyser.”

Practical Scheme of Work

You also need to complete experiments and experimental reports as a part of any IB Science course. For SL, there is 40 hours of material. For HL, there is 60 hours of material. Here are the activities:

  • Practical activities—20 hours for SL and 40 hours for HL
    • Lab work in class counts towards these hours
  • Individual investigation (internal assessment-IA)—10 hours for SL and HL
    • A lab project along with a report that counts as 20% of your IB exam scores (written exam counts for the other 80%)
  • Group 4 Project—10 hours for SL and HL
    • Students are separated into groups and must conduct an experiment and write a report.

Hopefully, yours won’t end in smoke!

What’s Next?

Curious about how you can use your chemistry knowledge outside the classroom? Try out these three recipes for slime and see which combination of ingredients has what effect! And if after doing this your kitchen mysteriously comes down with a case of the clogged drains, you’ll want to learn how to use muriatic acid safely and effectively to solve the problem.

Are you hoping to squeeze in some extra IB classes? Learn about the IB courses offered online.

Studying for the SAT? Check out our complete guide to the SAT. Taking the SAT in the next month? Check out our guide to cramming.

Not sure where you want to go to college? Check out our guide to finding your target school.

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